Azido(benzoylacetonato-κ2 O,O′)[1-phenyl-3-(2-pyridylmethylimino)but-1-en-1-olato-κ3 N,N′,O]cobalt(III)
نویسندگان
چکیده
In the title complex, [Co(C(16)H(15)N(2)O)(C(10)H(9)O(2))(N(3))], the Co(II) atom adopts an octa-hedral coordination geometry by a tridentate Schiff base, a bidentate benzoyl-acetonate and an azide ligand. The imine N atom of the tridentate ligand is trans to the benzoyl O atom of the bidentate ligand and the azide ligand is trans to the acetyl O atom of the bidentate ligand. Non-classical intra-molecular C(ar-yl)-H⋯O hydrogen bonds are present in the structure.
منابع مشابه
Bis(μ-3,5-dinitro-2-oxidobenzoato)-κ3 O 1,O 2:O 1;κ3 O 1:O 1,O 2-bis[aqua(2-phenyl-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2 N 7,N 8)cobalt(II)]
In the title compound, [Co(2)(C(7)H(2)N(2)O(7))(2)(C(19)H(12)N(4))(2)(H(2)O)(2)], the Co(II) atom is six-coordinated by two N atoms from a 2-phenyl-1H-1,3,7,8,-tetraaza-cyclo-penta-[l]phenanthrene (L) ligand, three O atoms from two 3,5-dinitro-2-oxidobenzoate (3,5-dinitro-salicylate or DNSA) ligands and one O atom from a water mol-ecule in a distorted octa-hedral geometry. The Co(II) atoms are ...
متن کاملCrystal structure of bis{μ-1-[(E)-(3-methoxyphenyl)diazenyl]naphthalen-2-olato-κ3 N 2,O:O}bis({1-[(E)-(3-methoxyphenyl)diazenyl]naphthalen-2-olato-κ2 N 2,O}copper(II))
The title dinuclear Cu(II) complex, [Cu2(C17H13N2O2)4], is located on an inversion centre. The Cu(II) atoms are each five-coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from two bidentate ligands and one bridging O atom from another ligand. In the dinuclear complex, the Cu⋯Cu separation is 3.366 (3) Å. In the crystal, complex mol-ecules are linked via weak C...
متن کاملTetrakis(μ2-3,4-dimethoxyphenylacetato)-κ3 O,O′:O′;κ3 O:O:O′;κ2 O:O′;κ2 O:O′-bis[(3,4-dimethoxyphenylacetato-κ2 O,O′)(1,10-phenanthroline-κ2 N,N)thulium(III)]
In the title centrosymmetric dinuclear complex, [Tm(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)], the unique Tm(III) ion is coordin-ated by five 3,4-dimethoxy-phenyl-acetate (DMPA) ligands and and a bis-chelating 1,10-phenanthroline (phen) ligand via seven O atoms and two N atoms, forming a distorted tricapped trigonal-prismatic environment. The DMPA ligands coordin-ate in the bis-chelate, bridging...
متن کامل(3-Benzoyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-olato-κ2 O,O)bis[2-(2-pyridyl)phenyl-κ2 C 1,N]iridium(III)
The title compound, [Ir(C(11)H(8)N)(2)(C(17)H(19)O(2))], has an octa-hedral coordination geometry around the Ir(III) atom, retaining the cis-C,C,trans-N,N chelate disposition of the two 2-phenyl-pyridine ligands. The chelate rings are nearly mutually perpendicular [the inter-planar angles range from 85.48 (17) to 89.17 (19)°]. The two 2-(2-pyrid-yl)phenyl ligands are approximately planar, with ...
متن کاملBis(4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olato-κ2 O,O′)bis(ethanol-κO)cobalt(II)
The title compound, [Co(C(17)H(13)N(2)O(2))(2)(C(2)H(5)OH)(2)], is a Co(II) complex with two 4-benzoyl-3-methyl-1-phenyl-1H-pyrazol-5-olate (BMPP) ligands and two coordinating ethanol mol-ecules. In the asymmetric unit, there are two half mol-ecules, with the Co(II) atoms located on inversion centres. The two cobalt complexes have slightly different geometries and in one, the ethyl group of the...
متن کامل